A symmetric complex [NiL2(H2O)2]Cl2, where L = 2-picolylamine was synthesized and characterized by spectroscopic and structural methods. Single crystal X-ray studies reveal that the Ni(II) center located in a pseudo-octahedral N4O2 environment with bidentate ligands L positioned in basal and two water molecules in the apical position. The complex is solvatochromic, ionochromic and thermochromic...

This paper is designed to examine the binding behavior of Coumarin with bovine -casein (βCN) through fluorescence spectroscopy and molecular modeling techniques. The data analysis on fluorescence titration experiments at various temperatures represents the enthalpy driven nature for the formation of Coumarin–βCN complex and the prevailed role of hydrogen bonds and van der Waals interactions in...

Natural selection in photosynthesis has engineered tetrapyrrole based, nanometer scale, light harvesting and energy capture in light-induced charge separation. By designing and creating nanometer scale artificial light harvesting and charge separating proteins, we have the opportunity to reengineer and overcome the limitations of natural selection to extend energy capture to new wavelengths and...

Verification problems are often expressed in a language which mixes several theories. A natural question to ask is whether one can use decision procedures for individual theories to construct a decision procedure for the union theory. In the cases where this is possible one has a powerful method at hand to handle complex theories effectively. The setup considered in this thesis is that of one b...

the emerging contaminants are commonly derived from municipal, agricultural, and industrialwastewater sources and pathways. these compounds are polar and poorly biodegradable. the dynamicremoval of atenolol from aqueous solutions by activated carbon in fixed bed column systems was investigated. as far as we know, this is the first study reporting the decontamination by adsorption in fixed bed o...