The mechanism of the self-reaction of HCO radicals is investigated by using high-level quantum-chemical methods including M05-2X, CCSD, CCSD(T) and CRCC(2,3). Next, the rate coefficients for several product channels as a function of pressure and temperature are computed by employing statistical rate theories. Four important product channels are predicted to be CO + CO + H2, HCOH + OH, cis-(HCO)...

introduction: cholesterol and fatty acids are two important components of the lipids. various fatty acids have different effects on plasma lipoproteins. consumption of saturated fatty acids tends to increase total plasma and ldl cholesterol levels. while  polyunsaturated fatty acids reduce both ldl and hdl cholesterol, edible oil rich in monounsaturated fatty acid (mufa) however, tend to lower ...

BACKGROUND High violent mortality rate in Russia and its profound fluctuation over recent decades have attracted considerable interest. A mounting body of evidence points to the binge drinking pattern as a potentially important contributor to the violent mortality crisis in Russia. In line with this evidence, we assume that higher level of vodka consumption in conjunction with binge drinking pa...

With an ever-increasing number of briefer interactions with a larger number of different “things”, innovative perspectives on authentication could be helpful. Ideally, authentication solutions are designed to balance requirements of security with those of usability, with the latter including cognitive ability for choosing credentials such as passwords, and memorability of those credentials. Som...

labonté et al provide an insightful analysis of the trans-pacific partnership (tpp) and its impact on a selection of important health determinants. their work confirms concerns raised by previous analyses of leaked drafts and offers governments serious and timely reasons to carefully consider provisions of the agreement prior to moving forward with ratification. it also contributes more general...