ethylene was homopolymerized over ziegler-natta catalyst and the homopolymerization was modeled using moment equations. mechanism was modeled according to five different reaction centers of catalyst. for each center, there are different reaction rate coefficients; therefore the final product of each center would be expected to be different. modeling results showed good conformity to the experim...

A comprehensive 3D coupled mathematical model is developed to study the microwave assisted thermocatalytic decomposition of methane with activated carbon as the catalyst. A simple reaction kinetic model for methane conversion (accounting for catalyst deactivation) is developed from previously published experimental data and coupled with the governing equations for the microwaves, heat transfer,...

Fischer-Tropsch synthesis is one of the most important catalytic reactions that convert the synthetic gas to light and heavy hydrocarbons. One of the main issues is selecting the type of reactor. The slurry bubble reactor is suitable choice for FischerTropsch synthesis because of its good qualification to transfer heat and mass, high durability of catalyst, low cost maintenance and repair. The ...

In this research mass transfer coefficient under jetting regime in different directions (from dispersed to continuous and continuous to dispersed phase) has been studied using an experimental setup. n-Butanol-succinic acid-water with low interfacial tension has been selected as experimental chemical system. The effects of various parameters such as jet velocity, nozzle diameter and the heig...

The main objective of this work is to upgrade a diesel oil sample from Shiraz Oil Refining Co. (SORC) to reduce the sulfur content, as well as break the kinematic viscosity of the feedstock. Effects of several operating parameters including volume of hydrogen peroxide/acetic acid as an oxidant mixture, amounts of tetraoctylammonium bromide as a phase transfer agent (PTA) and phosphotungstic aci...

Trifluoromethylated organic compounds, especially chiral quaternary alcohols bearing trifluoromethyl group are of important intermediates in drugs, agrochemicals and etc.An efficient epoxidation of β-CF3-β,β-disubstituted unsaturated ketones (6) has been developed with environmental benign hydrogen peroxide as the oxidant and F5-substituted chiral qua...

Nano-dispersed Fe and Fe3O4 on reduced graphene oxide (Fe /Fe3O4-RGO) was prepared and characterized. The prepared Fe/Fe3O4-RGO was used as a magnetically separable Fenton-like catalyst and showed superior catalytic activity compared to Fe3O4-RGO and Fe3O4 as well as other Fenton-like catalysts for the removal of phenol. The Fe/Fe3O4-RGO achieved 100% removal efficiency for phenol within 30 min...

In this study, the hydrolytic reaction mechanism of HPNP by two effective mononuclear Zn(II) catalysts was explored by using density functional calculations. With the assumption that the active catalyst is in Zn-aqua form, the water-assisted proton transfer mode was found to be energetically the most favorable one for both the catalysts among three possible reaction pathways. The rate-limiting ...