Mohammad Ali Zolfigol
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran.
[ 1 ] - Application of silica vanadic acid as a dual Lewis and Bronsted acid catalytic ability in Dakin West reaction
Silica Vanadic Acid, SVA, (oxo-vanadium has been supported on silica) as a dual Lewis and Bronsted acid ability was prepared and efficiently catalyzed one-pot multi-component condensation of enolizable ketones or alkyl acetoacetates with aromatic aldehydes, acetonitrile and acetyl chloride. The described reaction was produced β-acetamido ketone or ester derivatives in high to excellent yields i...
[ 2 ] - Friedel–Crafts synthesis of triarylmethanes over 3-methyl-1-sulfonic acid imidazolium tetrachloroaluminate under solvent-free conditions
Friedel–Crafts synthesis of triarylmethanes over 3-methyl-1-sulfonic acid imidazolium tetrachloroaluminate under green conditions:In this work, Friedel–Crafts (FC) alkylation of various arenes with aromatic aldehydes catalyzed by 3-methyl-1-sulfonic acid imidazoliumtetrachloroaluminate {[Msim]AlCl4}, as a green catalyst, to prepare triarylmethanes (TAMs) has been carried out. Some aromatic alde...
[ 3 ] - 1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) as an organocatalyst for the silylation/desilylation reaction
1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) was used as a chemoselective and effective organocatalyst for the silylation of hydroxyl groups as well as desilylation of trimethylsilyl ethers under mild conditions at room temperature with good to excellent yields.
[ 4 ] - Synthesis of Poly-Substituted Quinolines via Friedländer Hetero-Annulation Reaction Using Silica-Supported P2O5 under Solvent-Free Conditions
A highly efficient, simple and green solvent-free protocol for the preparation of poly-substituted quinolines via Friedländer hetero-annulation reaction between 2-aminoaryl ketones and carbonyl compounds in the presence of silica-supported P2O5 (P2O5 / SiO2) is described. In this method, the title compounds are obtained in high to exc...
[ 5 ] - An Efficient Protocol for the Synthesis of Carboacyclic Nucleosides via Aza-Conjugate Addition Reaction
A new efficient method for the synthesis of carboacyclic nucleosides as biologically interesting compounds via aza-conjugate addition of pyrimidine nucleobases to a,β-unsaturated esters in the presence of catalytic amount of LiOH.H2O (1.2-4.8 mol%) under microwave irradiation is described. This method affords the title compounds in good to excellent yields and i...
[ 6 ] - A Reinvestigation of Nitration of Phenols with Metal Nitrates under Non-Aqueous and Aprotic Conditions
Nitration of phenol and various 4-substituted phenols with Cu(NO3)2.3H2O, Cu(NO3)2.3H2O/SiO2, 9H2O and Cr(NO3)2. 9H2O in different anhydrous organic solvents are investigated. High selectivity ratio of para vs ortho isomers has been observed. Mono- and dinitro compounds f...
[ 7 ] - Hydroxylamine-O-sulfonic Acid (HOSA): As a Task Specific Catalyst for the Synthesis of 1,8-Dioxo-octahydroxanthenes under Mild, Green and Solvent-free Condition
A highly efficient procedure for the synthesis of 1,8-dioxo-octahydroxanthenes under mild, green and solvent-free condition by using HOSA as a dual role catalyst is described. This is the first report of catalytic activity of HOSA.
[ 8 ] - ایزاتین-N-سولفونیک اسید به عنوان کاتالیزوری جدید، کارآمد و قابل بازیافت برای تهیه 2-آمیدوآلکیل فنلها تحت شرایط بدون حلال
در این پژوهش، روشی ساده و بسیار موثر برای سنتز 2-آمیدوالکیل فنلها با استفاده از ایزاتین-N-سولفونیک اسید به عنوان یک کاتالیزور اسیدی جامد گزارش شده است. 2-آمیدوآلکیل فنلها از طریق واکنش تراکمی سه جزیی فنلها با آریلآلدهیدهای گوناگون و آمیدها، تحت شرایط بدون حلال در مجاورت کاتالیزور ایزاتین-N-سولفونیک اسید در دمای 90 درجه سانتی گراد با بازده بالا و در مدت زمان کوتاه تهیه شدند.
[ 9 ] - A new approach for the synthesis of 3,4-dihydropyrano[c]chromenes and biscoumarins using {[2,2’-BPyH][C(CN)3]2} as a bifunctional nanostructured ionic liquid catalyst
[2,2'-Bipyridine]-1,1'-diium tricyanomethanide {[2,2'-BPyH][C(CN)3]2} as a bifunctional nanostructured ionic liquid catalyst (0.5 mol%) was used for the synthesis of 3,4-dihydropyrano[c]chromenes (14 examples) under solvent-free condition at room temperature in high yield (82-91%) and short reaction time. In addition, the described ionic liquid catalyst was also applied for the synthesis of bis...
[ 10 ] - A novel nano perfluoro ionic liquid as an efficient catalyst in the synthesis of chromenes under mild and solvent-free conditions
1-Methyl-1H-imidazol-3-ium 2,3,4,5,6-pentafluorophenolate [mim]C6F5O as a novel nano ionic liquid was designed, synthesized and characterized by using various techniques such as Fourier transform spectroscopy infrared (FT-IR), nuclear magnetic resonance (NMR), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ener...
[ 11 ] - Application of silica vanadic acid as a dual Lewis and Bronsted acid catalytic ability in Dakin West reaction
Silica Vanadic Acid, SVA, (oxo-vanadium has been supported on silica) as a dual Lewis and Bronsted acid ability was prepared and efficiently catalyzed one-pot multi-component condensation of enolizable ketones or alkyl acetoacetates with aromatic aldehydes, acetonitrile and acetyl chloride. The described reaction was produced β-acetamido ketone or ester derivatives in high to excellent yields i...
[ 12 ] - Friedel–Crafts synthesis of triarylmethanes over 3-methyl-1-sulfonic acid imidazolium tetrachloroaluminate under solvent-free conditions
Friedel–Crafts synthesis of triarylmethanes over 3-methyl-1-sulfonic acid imidazolium tetrachloroaluminate under green conditions:In this work, Friedel–Crafts (FC) alkylation of various arenes with aromatic aldehydes catalyzed by 3-methyl-1-sulfonic acid imidazoliumtetrachloroaluminate {[Msim]AlCl4}, as a green catalyst, to prepare triarylmethanes (TAMs) has been carried out. Some aromatic alde...
[ 13 ] - 1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) as an organocatalyst for the silylation/desilylation reaction
1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) was used as a chemoselective and effective organocatalyst for the silylation of hydroxyl groups as well as desilylation of trimethylsilyl ethers under mild conditions at room temperature with good to excellent yields.
[ 14 ] - A Multi-Objective Optimization of Artichoke (Cynara Scolymus L.) Leaves Aqueous Extraction Dehydration Through a Novel Spray Drying Approach Using Response Surface Methodology
In this study, Cynara scolymus L. leaves aqueous extract powder was produced using a novel spray drying approach by incorporation of ongoing ultrasonic atomization and vacuumed drying chamber. A Response Surface Methodology (RSM)-based central composite face-centered design was employed for optimization of the operating conditions of the ultrasonic vacuum spray dryer. The independent variab...
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